To create and print the mailing labels, you must first prepare the worksheet data in Excel and then use Word to configure, organize, review, and print the mailing labels.
Select New Document. Word opens a new document that contains a table with dimensions that match the label product. If gridlines are not displayed, go to Layout > Align > View Gridlines to turn gridlines on. Type the information you want in each label. Go to File > Print and select the Print button. You can save the document for future use.
Word for the web doesn't directly support creating labels, but you can create labels from a template. For label templates, go to templates.office.com and search for labels.
You can create the labels as a report within Access, or you can "merge" the data with a Microsoft Word document and then print the labels from Word. This article outlines the steps involved.